By Gregory D. Botsaris (auth.), J. W. Mullin (eds.)
Industrial Crystallization Symposia were equipped through the Crystallization study staff on the Czechoslovak learn Institute for Inorganic Chemistry, Usti nad Labem, in view that 1960. through the years, the expanding acclaim for the unit operation of crystallization has been sincerely confirmed via the regular bring up in numbers of either the papers awarded and the attendances on the conferences. The sixth Symposium (1-3 September 1975) was once equipped together with the eu Federation of Chemical Engineering operating get together on Crystallization, and the forty four papers offered have been prepared into 4 periods - A: Secondary Nucleation, B: Crystal progress Kinetics, C: Crystal behavior amendment, D: Crystallizer layout, E: Indus trial Crystallizer Operation and Case experiences. an analogous groupings are preserved during this edited model of the court cases. this is often the 1st time that the economic Crystallization Symposium papers have seemed in a single quantity. After the fifth (1972) Symposium, authors we.re inspired to publish their papers to a world magazine focusing on crystallization. notwithstanding, the implications weren't altogether passable in that lower than one 3rd of the papers awarded on the assembly have been provided for attention. This time, hence, the organizing committee determined to aim to maintain the papers jointly via making preparations for his or her ebook via Plenum Press.
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G' and R- are the growth rate and crystal size. C. ) = J(Y 0n 1 (1-£ 2Y -1/ 3 ) S = P(1-Yl-3) 01 f = superficial y3-b dy [1+ (0-1)( Y3_1 ) IYl 3 -1)] n fMb,C1(0 -1) (10) where velocity of solution on solvent basis, M = molecular weight, P = production rate, kv & ka shape factors, y = dimensionless crystal size (R-/R-1), 0 = dimensionless supersaturation (b,C1/b,C2) , £ = voidage, Subscripts 1 and 2 are top of the crystallizer. Design Procedure Crystallization rate, product size (crystal size at the bottom) and voidage at top and bottom are fixed.
Instn. Chern. , 51, (1973),72. 4 Randolph A D and Cise M D, AIChEJ. 18, (1972), 798. 5 Randolph A D and Sikdar S K, AIChEJ. 20, (1974),410. 6 Garabedian H and Strickland-Constable R F, J. Crystal Growth, 13/14, (1972), 506. 7 Wey J S and Terwilliger J P, AIChEJ. 20, (1974), 1219. 8 Rosen H N, AICbEJ, 20, (1974), 388. 9 Garabedian H and Strickland-Constable R F, J. Crystal Growth 12, (1972), 53. F. 2 ergs of work per nucleus. Calculations are given in this paper to examine some of the consequences which would result from the assumption that the nuclei are formed by fracture of the parent crystal, and that they are of the order of size given by the Gibbs-Thomson equation.
33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. D. , and R. Conti, Kristal und Technik, 8, 931 (1973). , "Kinetic Theory of Liquids", p. 384, Dover Pub. F. Strickland-Constable, J. Crystal Growth, 13/14, 506 (1972). F. Strickland-Constable, J. Crystal Growth, 22, 188 (1974). B. Head, J. Crystal Growth, ~, 349 (1970). L. McCabe, AIChE Symposium Series, 68 (121), 31 (1972). W. T. F. Sarofim, AIChE J •• 20, 855 (1974). O~ Soviet Physics-Crystallography, I, 456 (1956). A. F. Str~ckland-Constable, J.
Industrial Crystallization by Gregory D. Botsaris (auth.), J. W. Mullin (eds.)