Download e-book for kindle: Lanthanide and Actinide Chemistry and Spectroscopy by Norman M. Edelstein (Eds.)

By Norman M. Edelstein (Eds.)

ISBN-10: 084120568X

ISBN-13: 9780841205680

ISBN-10: 0841207062

ISBN-13: 9780841207066

content material: Nonclassical activation of carbon monoxide by means of organoactinides / Tobin J. Marks, Juan M. Manriquez, Paul J. Fagan, Victor W. Day, Cynthia S. Day, and Sarah H. Vollmer --
Alkyl, hydride, and similar bis(trimethylsilyl)amide derivatives of the 4f- and 5f- block metals / Richard A. Andersen --
natural derivatives of the f-block parts: a quest for f-orbital participation and destiny point of view / Takeshi Miyamoto and Minoru Tsutsui --
Synthesis and spectroscopy of novel mixed-ligand organolanthanide complexes / R. Dieter Fischer and Gudrun Bielang --
Cyclooctatetraeneactinide(IV) bis-borohydrides / Jeffrey P. sunlight, Andrew Streitwieser, Jr., and Norman M. Edelstein --
Nuclear magnetic resonance reviews of uranocenes / Wayne D. Luke and Andrew Streitwieser, Jr. --
particular sequestering brokers for the actinides / Kenneth N. Raymond, William L. Smith, Frederick L. Weitl, Patricia W. Durbin, E. Sarah Jones, Kamal Abu-Dari, Stephen R. Sofen, and Stephen R. Cooper --
internal- vs. outer-sphere complexation of lanthanide (III) and actinide (III) ions / Gregory R. Choppin --
Actinides : d-or f-transition metals? / Werner Müller --
Vapor strain and thermodynamics of actinide metals / John W. Ward, Phillip D. Kleinschmidt, Richard G. Haire, and David Brown --
ideas of microchemistry and their functions to a couple transcurium components at Berkeley and Oak Ridge / J.R. Peterson --
Chemistry of the heaviest actinides : fermium, mendelevium, nobelium, and lawrencium / E.K. Hulet --
Hypersensitive transitions in f-electron structures / B.R. Judd --
Lanthanide and actinide lasers / Marvin J. Weber --
digital constitution of actinyl ions / R.G. Denning, J.O.W. Norris, I.G. brief, T.R. Snellgrove, and D.R. Woodwark --
Synthesis and characterization of protactinium(IV), neptunium(IV), and plutonium (IV) borohydrides / Rodney H. Banks and Norman M. Edelstein --
Optical homes of actinide and lanthanide ions / Jan P. Hessler and W.T. Carnall --
Photochemistry of uranium compounds / Robert T. Paine and Marcia S. Kite --
Multistep laser photoionization of the lanthanides and actinides / E.F. Worden and J.G. Conway --
Photoelectron spectra of actinide compounds / B.W. Veal and D.J. Lam.

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Extra info for Lanthanide and Actinide Chemistry and Spectroscopy

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A c r y s t a l s t r u c t u r e of the lanthanum d e r i v a t i v e has a l s o been described. The d i s s o c i a t i o n pressure i n gas phase of Pt^PO complex i s a p p r e c i a b l e as the base-free compound sublimes when heated i n vacuum a t 80-100°C. In c o n t r a s t , the uranium t r i s s i l y l a m i d e does not y i e l d i s o l a b l e complexes with Bu^C, ButCN, p y r i d i n e , or trimethylphosphine oxide (13). The i n a b i l i t y to i s o l a t e c o o r d i n a t i o n complexes with a v a r i e t y of Lewis bases i s r a t h e r s u r p r i s i n g s i n c e uranium (III) i s l a r g e r 3 2 3 2 2 3 2 2 36 LANTHANIDE AND ACTINIDE CHEMISTRY AND SPECTROSCOPY than to i t s oogenic, neodymium (III) (17).

Bradley, D. C. J. Chem. Soc. Chem. , 1974, 29. Andersen, R. A . ; Jones, R. A . ; Wilkinson, G. J. Chem. Soc. , 1978, 446. ; Whitesides, G. M. J. Am. Chem. , 1979, 100, 2732. Turner, H. ; Simpson, S. ; Andersen, R. A. J. Am. Chem. , 1979, 101, 2782. a) Brown, H. C. "Boranes in Organic Chemistry"; Cornell University Press: Ithaca, 1972, p. 265. b) Brown, H. C . ; Scouten, C. G . ; Wang, K. K. J. Org. , 1979, 44, 2589. G e l l , K. I . ; Schwartz, J . J . Am. Chem. , 1978, 100, 3246. McAlister, D.

This i s not unexpected since the a c t i n i d e elements are q u i t e e l e c t r o positive. P o s s i b l y the most f a s c i n a t i n g r e a c t i o n o f the hydrides so f a r discovered i s t h e i r f a c i l e exchange o f a l l f i f t y - f i v e hydrogen atoms with deuterium under one atmosphere o f deuterium pressure a t room temperature i n pentane (21). The conversion 42 LANTHANIDE AND [(Me Si) N] MH + D 3 2 3 ACTINIDE CHEMISTRY AND > 2 DM{N[Si (CD3)3] > 2 3 i s 92-97% complete.

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Lanthanide and Actinide Chemistry and Spectroscopy by Norman M. Edelstein (Eds.)


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